Second, the present invention provides a large-scale industrial production process with low production cost, high efficiency, energy saving, and stable product quality with an annual production capacity of several hundred thousand tons. Selective leaching of zinc by ammonia method, combined with ammonium persulfate iron removal, vulcanization method and zinc powder replacement method to remove heavy metal elements such as nickel, copper, lead, cadmium and arsenic, and metathesis reaction to obtain nZnS-B a S0 4 crystal filter cake. The nano-Lide powder product is obtained by directly drying and pulverizing without high-temperature calcination. The resulting product is of good quality and industrially operable.
Lithopone was discovered in the 1870s by DuPont. It was manufactured by Krebs Pigments and Chemical Company and other companies.[2] The material came in different seals, which varied in the content of zinc sulfide. Gold seal and Bronze seals contain 40-50% zinc sulfide, offering more hiding power and strength.[3] Although its popularity peaked around 1920, approximately 223,352 tons were produced in 1990. It is mainly used in paints, putty, and in plastics.[1]
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