There is a British Standard laid down for the control of synthetic rubbers. BS 3574 (1989) helps to determine shelf life – for instance, Nitrile (NBR) and Polyacrylic (ACM) are Group ‘B’ rubbers and have a 7-year life, whilst Silicone (VMQ) and Fluoroelastomers (Viton®) are Group ‘C’ rubbers and have a 10-year shelf life. PTFE and Leather do not come into this category but like the others should be kept in the original packing for as long as possible away from direct light, dust, and humidity. Ozone, which can also be produced by battery-driven forklift trucks has a very bad effect on synthetic rubbers. Finally, protect the sealing lip – DO NOT hang the seals on nails, wire etc.
Vulcanizates of several fluoroelastomers, listed in Table 14.1, were exposed to a standard 5W-30 engine oil, ASTM Service Fluid 105, for up to 6 weeks at 150°C (302°F).5 The oil was changed weekly, but was not aerated. Retained elongation was measured after exposure for 1, 2, 3, and 6 weeks; data are shown in Fig. 14.3. The results indicate that bisphenol-cured FKM-A500 VDF/HFP copolymer, FKM-B600 VDF/HFP/TFE terpolymer, and peroxide-cured FEPM-7456 TFE/P/VDF terpolymer lost most of their original elongation over the course of the test exposure, indicating considerable additional cross-linking occurred by reaction with amine- and phenol-containing oil additives. The other fluoroelastomers showed better retention of elongation, being much less susceptible to additional crosslinking. Note that FEPM-7456 contains a high level of VDF (about 30%), while FEPM-7506 contains a relatively low VDF level (10–15%) to serve as cure site for bisphenol curing. The other FEPM types contain no VDF.